AustralieFrV1, Main, Exploration, bibRecord, 006355

Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Identifieur interne : 006355 ( Main/Exploration ); précédent : 006354; suivant : 006356

Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Auteurs : Michael I. Bruce [Australie] ; Damien Joly [Australie, France] ; Brian W. Skelton [Australie] ; Allan H. White [Australie]

Source :

ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2011-05.

RBID : ISTEX:A17A68568A3E2A566BA725AA9D8365715A3979F5

English descriptors

KwdEn :
- Acta crystallogr, Cation, Chem, Data centre, Hydrogen atoms, Ligand, Molecular structure, Short communication, Structural study, Structure determination, Verlag gmbh, Zinc chloride.
Teeft :
- Acta crystallogr, Cation, Chem, Data centre, Hydrogen atoms, Ligand, Molecular structure, Short communication, Structural study, Structure determination, Verlag gmbh, Zinc chloride.

Abstract

The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6‐C8‐ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl2. (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).

Url:

https://api.istex.fr/document/A17A68568A3E2A566BA725AA9D8365715A3979F5/fulltext/pdf

DOI: 10.1002/zaac.201000447

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001E57
to stream Istex, to step Curation: 001E57
to stream Istex, to step Checkpoint: 000774
to stream Main, to step Merge: 006731
to stream Main, to step Curation: 006355

Le document en format XML

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<front><div type="abstract" xml:lang="en">The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6‐C8‐ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl2.  (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).</div>
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Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri